Download A Guide To Chalcogen-Nitrogen Chemistry by Tristram Chivers PDF

By Tristram Chivers

Chalcogen-nitrogen chemistry consists of the examine of compounds that convey a linkage among nitrogen and sulfur, selenium or tellurium atoms. Such reports have either basic and useful value. A advisor to Chalcogen-Nitrogen Chemistry examines the function of chalcogen-nitrogen compounds in parts starting from solid-state inorganic chemistry to biochemistry. The dialogue covers basic questions about the bonding in electron-rich platforms, in addition to capability useful functions of polymers and fabrics with novel magnetic or electric homes. This e-book is the one account of this significant subject to seem within the final twenty-five years, and paired with its broad literature insurance of very contemporary advancements, this finished consultant is vital for an individual operating within the box. The remedy is exclusive in delivering a comparability of sulfur, selenium and tellurium structures, with an technique meant to stress common recommendations that may be worthwhile to the non-specialist. each one bankruptcy is designed to be self-contained, and there are vast cross-references among chapters.

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Rihs, D. Schomburg, G. Shoham, D. Wenkert and R. B. Woodward, J. Am. Chem. , 103, 1540 (1981). 28 A Guide to Chalcogen–Nitrogen Chemistry 28. K. Seppelt, Inorg. , 12, 2837 (1973). 29. J. Bojes, T. Chivers and I. Drummond, Inorg. , 18, 203 (1978). 30. F. A. Kennett, G. K. MacLean, J. Passmore and M. N. S. Rao, J. Chem. , 851 (1982). 31. J. Siivari, T. Chivers and R. S. Laitinen, Angew. , Int. , 31, 1518 (1992). 32. A. J. Banister, R. G. Hey, G. K. MacLean and J. Passmore, Inorg. , 21, 1679 (1982).

6). 6), is formed as an intermediate in the synthesis of S4N4. 2 From Amines and Amido–Lithium or Sodium Reagents The reactions of amines or amido-lithium compounds with chalcogen halides provide a convenient source of a variety of important chalcogennitrogen reagents. The reactions of LiN(SiMe3)2 with SCl2, Se2Cl2 or TeCl4 in hexane or diethyl ether produce the chalcogen(II) diamides E[N(SiMe3)2]2 (E = S, Se, Te)11, 12 in good yields (Eq. 3). 3) The reactivity of the Si–N bonds in these reagents can be utilized in further synthesis of chalcogen-nitrogen compounds.

W. Bats, R. Gleiter, G. Hartman, R. Mews, M. Eckert-Maksiü H. Oberhammer and G. M. Sheldrick, Chem. , 118, 3781 (1985). 6. E. G. Awere, N. Burford, C. Mailer, J. Passmore, M. J. Schriver, P. S. White, A. J. Banister, H. Oberhammer and L. H. Sutcliffe, J. Chem. , Chem. , 66 (1987). 7. (a) E. Jaudas-Prezel, R. Maggiulli, R. Mews, H. Oberhammer, T. Paust and W-D. Stohrer, Chem. , 123, 2123 (1990); (b) E. Jaudas-Prezel, R. Maggiulli, R. Mews, H. Oberhammer and W-D. Stohrer, Chem. , 123, 2117 (1990).

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